415 research outputs found
Surface state engineering of molecule-molecule interactions
Engineering the electronic structure of organics through interface
manipulation, particularly the interface dipole and the barriers to charge
carrier injection, is of essential importance to improved organic devices. This
requires the meticulous fabrication of desired organic structures by precisely
controlling the interactions between molecules. The well-known principles of
organic coordination chemistry cannot be applied without proper consideration
of extra molecular hybridization, charge transer and dipole formation at the
interfaces. Here we identify the interplay between energy level alignment,
charge transfer, surface dipole and charge pillow effect and show how these
effects collectively determine the net force between adsorbed porphyrin 2H-TPP
on Cu(111). We show that the forces between supported porphyrins can be altered
by controlling the amount of charge transferred across the interface accurately
through the relative alignment of molecular electronic levels with respect to
the Shockley surface state of the metal substrate, and hence govern the
self-assembly of the molecules
Ecological model of extinctions
We present numerical results based on a simplified ecological system in
evolution, showing features of extinction similar to that claimed for the
biosystem on Earth. In the model each species consists of a population in
interaction with the others, that reproduces and evolves in time. Each species
is simultaneously a predator and a prey in a food chain. Mutations that change
the interactions are supposed to occur randomly at a low rate. Extinctions of
populations result naturally from the predator-prey dynamics. The model is not
pinned in a fitness variable, and natural selection arises from the dynamics.Comment: 16 pages (LaTeX type, RevTeX style), including 6 figures in gif
format. To be published in Phys. Rev. E (prob. Dic. 96
Percolation on two- and three-dimensional lattices
In this work we apply a highly efficient Monte Carlo algorithm recently
proposed by Newman and Ziff to treat percolation problems. The site and bond
percolation are studied on a number of lattices in two and three dimensions.
Quite good results for the wrapping probabilities, correlation length critical
exponent and critical concentration are obtained for the square, simple cubic,
HCP and hexagonal lattices by using relatively small systems. We also confirm
the universal aspect of the wrapping probabilities regarding site and bond
dilution.Comment: 15 pages, 6 figures, 3 table
Racial Differences in the Effects of Hormone Therapy on Incident Open-Angle Glaucoma in a Randomized Trial
Purpose: We conducted a secondary analysis of a randomized, placebo-controlled trial to test if hormone therapy (HT) altered the risk of open-angle glaucoma (OAG), and if the risk reduction varied by race. Design: Secondary analysis of randomized controlled trial data. Methods: We linked Medicare claims data to 25 535 women in the Women's Health Initiative. Women without a uterus were randomized to receive either oral conjugated equine estrogens (CEE 0.625 mg/day) or placebo, and women with a uterus received oral CEE and medroxyprogesterone acetate (CEE 0.625 mg/day + MPA 2.5 mg/day) or placebo. We used Cox proportional hazards models to calculate hazard ratios (HR) and 95% confidence interval. Results: After exclusion of women with prevalent glaucoma or without claims for eye care provider visits, the final analysis included 8102 women (mean age = 68.5 ± 4.8 years). The OAG incidence was 7.6% (mean follow-up = 11.5 ± 5.2 years; mean HT duration = 4.4 ± 2.3 years). Increased age (P trend =.01) and African-American race (HR = 2.69, 95% CI = 2.13–3.42; white as a reference) were significant risk factors for incident OAG. We found no overall benefit of HT in reducing incident OAG (HR = 1.01, 95% CI = 0.79–1.29 in the CEE trial, and HR = 1.05, 95% CI = 0.85–1.29 in the CEE + MPA trial). However, race modified the relationship between CEE use and OAG risk (P interaction =.01), and risk was reduced in African-American women treated with CEE (HR = 0.49, 95% CI = 0.27–0.88), compared to placebo. Race did not modify the relation between CEE + MPA use and OAG risk (P interaction =.68). Conclusions: Analysis suggests that HT containing estrogen, but not a combination of estrogen and progesterone, reduces the risk of incident OAG among African-American women. Further investigation is needed
Self-organized criticality in deterministic systems with disorder
Using the Bak-Sneppen model of biological evolution as our paradigm, we
investigate in which cases noise can be substituted with a deterministic signal
without destroying Self-Organized Criticality (SOC). If the deterministic
signal is chaotic the universality class is preserved; some non-universal
features, such as the threshold, depend on the time correlation of the signal.
We also show that, if the signal introduced is periodic, SOC is preserved but
in a different universality class, as long as the spectrum of frequencies is
broad enough.Comment: RevTex, 8 pages, 8 figure
Eco-evolutionary dynamics on deformable fitness landscapes
Conventional approaches to modelling ecological dynamics often do not include evolutionary changes in the genetic makeup of component species and, conversely, conventional approaches to modelling evolutionary changes in the genetic makeup of a population often do not include ecological dynamics. But recently there has been considerable interest in understanding the interaction of evolutionary and ecological dynamics as coupled processes. However, in the context of complex multi-species ecosytems, especially where ecological and evolutionary timescales are similar, it is difficult to identify general organising principles that help us understand the structure and behaviour of complex ecosystems. Here we introduce a simple abstraction of coevolutionary interactions in a multi-species ecosystem. We model non-trophic ecological interactions based on a continuous but low-dimensional trait/niche space, where the location of each species in trait space affects the overlap of its resource utilisation with that of other species. The local depletion of available resources creates, in effect, a deformable fitness landscape that governs how the evolution of one species affects the selective pressures on other species. This enables us to study the coevolution of ecological interactions in an intuitive and easily visualisable manner. We observe that this model can exhibit either of the two behavioural modes discussed in the literature; namely, evolutionary stasis or Red Queen dynamics, i.e., continued evolutionary change. We find that which of these modes is observed depends on the lag or latency between the movement of a species in trait space and its effect on available resources. Specifically, if ecological change is nearly instantaneous compared to evolutionary change, stasis results; but conversely, if evolutionary timescales are closer to ecological timescales, such that resource depletion is not instantaneous on evolutionary timescales, then Red Queen dynamics result. We also observe that in the stasis mode, the overall utilisation of resources by the ecosystem is relatively efficient, with diverse species utilising different niches, whereas in the Red Queen mode the organisation of the ecosystem is such that species tend to clump together competing for overlapping resources. These models thereby suggest some basic conditions that influence the organisation of inter-species interactions and the balance of individual and collective adaptation in ecosystems, and likewise they also suggest factors that might be useful in engineering artificial coevolution
Processing of ultrafine-size particulate metal matrix composites by advanced shear technology
Copyright @ 2009 ASM International. This paper was published in Metallurgical & Materials Transactions A 40A(3) and is made available as an electronic reprint with the permission of ASM International. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplications of any material in this paper for a fee or for commercial purposes, or modification of the content of this paper are prohibited.Lack of efficient mixing technology to achieve a uniform distribution of fine-size reinforcement within the matrix and the high cost of producing components have hindered the widespread adaptation of particulate metal matrix composites (PMMCs) for engineering applications. A new rheo-processing method, the melt-conditioning high-pressure die-cast (MC-HPDC) process, has been developed for manufacturing near-net-shape components of high integrity. The MC-HPDC process adapts the well-established high shear dispersive mixing action of a twin-screw mechanism to the task of overcoming the cohesive force of the agglomerates under a high shear rate and high intensity of turbulence. This is followed by direct shaping of the slurry into near-net-shape components using an existing cold-chamber die-casting process. The results indicate that the MC-HPDC samples have a uniform distribution of ultrafine-sized SiC particles throughout the entire sample in the as-cast condition. Compared to those produced by conventional high-pressure die casting (HPDC), MC-HPDC samples have a much improved tensile strength and ductility.EP-SR
Isospin influences on particle emission and critical phenomenon in nuclear dissociation
Features of particle emission and critical point behavior are investigated as
functions of the isospin of disassembling sources and temperature at a moderate
freeze-out density for medium-size Xe isotopes in the framework of isospin
dependent lattice gas model. Multiplicities of emitted light particles,
isotopic and isobaric ratios of light particles show the strong dependence on
the isospin of the dissociation source, but double ratios of light isotope
pairs and the critical temperature determined by the extreme values of some
critical observables are insensitive to the isospin of the systems. Values of
the power law parameter of cluster mass distribution, mean multiplicity of
intermediate mass fragments (), information entropy () and Campi's
second moment () also show a minor dependence on the isospin of Xe
isotopes at the critical point. In addition, the slopes of the average
multiplicites of the neutrons (), protons (), charged particles
(), and IMFs (), slopes of the largest fragment mass number
(), and the excitation energy per nucleon of the disassembling source
() to temperature are investigated as well as variances of the
distributions of , , , , and . It
is found that they can be taken as additional judgements to the critical
phenomena.Comment: 9 Pages, 8 figure
Avalanche Dynamics in Evolution, Growth, and Depinning Models
The dynamics of complex systems in nature often occurs in terms of
punctuations, or avalanches, rather than following a smooth, gradual path. A
comprehensive theory of avalanche dynamics in models of growth, interface
depinning, and evolution is presented. Specifically, we include the Bak-Sneppen
evolution model, the Sneppen interface depinning model, the Zaitsev flux creep
model, invasion percolation, and several other depinning models into a unified
treatment encompassing a large class of far from equilibrium processes. The
formation of fractal structures, the appearance of noise, diffusion with
anomalous Hurst exponents, Levy flights, and punctuated equilibria can all be
related to the same underlying avalanche dynamics. This dynamics can be
represented as a fractal in spatial plus one temporal dimension. We develop
a scaling theory that relates many of the critical exponents in this broad
category of extremal models, representing different universality classes, to
two basic exponents characterizing the fractal attractor. The exact equations
and the derived set of scaling relations are consistent with numerical
simulations of the above mentioned models.Comment: 27 pages in revtex, no figures included. Figures or hard copy of the
manuscript supplied on reques
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